Originally posted by mcgregni As I understand it, in principle, it is the flash units Pentax 'TTL Dedication' that should determine its compatibility to work these functions, plus the remote power level control.
In principle, yes, but note that a V6II can work with other flash systems as well.
Most flashes supporting E-TTL (Canon), i-TTL (Nikon), P-TTL (Pentax) and I think some more, will support remote power level and zoom setting control.
Originally posted by mcgregni For P-TTL optical wireless working you don't need to set HS Sync mode on the slave flashes, only on the Master/Control flash. Now with radio triggering there's no 'Master' flash, do we need to set the Slave flashes to HS Sync mode ?
A system-dedicated flash should be set up as if you were using it on a camera.
My Metz 58 AF-2, for instance, does not require any setup. As soon as I turn on the V6II receiver, the Metz automatically switches into the right (P-TTL HSS) mode.
Manual flashes, or those that only support extra features through proprietary means (e.g., Godox flashes that do not have a Canon/Nikon dedication) require manually engaging their HSS mode, if you want to use them for HSS photography.
Originally posted by mcgregni In fact, I'm thinking also that the slaves would not need to be set to their Wireless mode at all, as that relates only to P-TTL wireless working (which we're not using in this case with the V6IIs).
Yes, as dfp771 already mentioned, off-camera flashes on V6II receiver units are essentially treated as if they were connected to a camera directly.
Originally posted by mcgregni And finally, is there a need to switch to HSS mode on either the V6II Tx or Rx, or both?
No, you can take manual control, if you like, but the default are auto modes that use standard-sync or HSS-sync depending on the shutter speed.
Originally posted by mcgregni That's interesting, and seems to be a change for Cactus ... The V6 required slave flashes to be set to P-TTL mode to control power levels.
The V6 mainly used an analogue interface to communicate with flashes. It was not able to speak the digital language specific to the respective flash systems.
In contrast, the V6II talks to flashes using their native digital protocol. It can thus achieve quite a bit more, such as putting them in the right mode and/or control the zoom setting.
I don't know whether the fact that the Metz 52 AF-1 can be put into any mode (including manual) and still work with a V6II translates to other flash models. I suspect not, but any standard/default mode should work without requiring manual intervention.