Originally posted by disord3r Button customizations (along with vast other settings) can differ between mode dial changes, so you might be able to get the customization you're after by copying your mode to USER1 or USER2 and changing it there. In TAv you can have raw change your file mode, but in USER1 it can do DOF preview (with all other settings identical). It requires a twist of the mode dial, but I think it's the best you'll get.
Actually, even easier than this... file format is something that can be customized between modes, so you can copy your preferred mode to USER1, leave RAW set to DOF preview in both modes, and set the default file format to RAW+JPG in USER1. Shoot as normal in your preferred mode, and then for that occasional shot that you want in raw, just twist to USER1 and everything will be as normal except for the file format change. You just have to remember to recompse the shot to get the ISO/EV/ap from before the twist, or make the twist before you compose.