Hiii
I am not sure what you have in mind, but you can definitely use CS3 to sketch over photos.
Working on no assumption at all :
- You can use the text tool (shortcut key 'T') to type words over your photo.
- You can use the brush tool (shortcut key 'B') to draw
- You can use the basic shapes tool (shortcut key 'U' to draw shapes such as lines and rectangles)
- If you want to keep the photo untouched, i recommend reading up on Photoshop layers. There must be tons of tutorials there.
- Remember that whenever you select a tool, its context menu will be displayed horizontally on the top bar. For example, if you select the brushes, the types of brush, its behaviour, opacity, etc will be displayed at the top bar.
- if the sketches are not turning out like you want them to be, play around with brush and brush sizes. There are hundreds of brushes, and you can customize every aspect of the brush such as the density of the ink, the flow of the ink, the shape of the brush, etc.
I hope that starts you in the right direction! cheers
