DA10-17 Fisheye zoom is not to be overlooked, because you can control the distortion to where it's minimal. Nice colors - almost like the DA15.
I think you've built the right kit so far. Just as you had to go with a prime at the long end with the DA*300 (DA*60-250 and DA*200 are both shorter and can't quite measure up in IQ), you may need to consider a prime at the wide end as well. I'll say up front there's no perfect solution if you need to go wider than 15mm and remain rectilinear.
The DA*300 and DA*50-135 are perfect solutions (more or less). The DA*16-50 isn't perfect, but it's the best you can do and is still very good. You'll probably have to settle on very good at the wide end too. I doubt the upcoming Pentax ~12-28 (which is possibly the new Tokina?) will change this situation.
The DA15 and DA10-17 create the nicest images, IMO. But the DA15 is just barely ultra-wide (though it's enough for me most of the time) and not everyone's looking for the variable distortion of the DA10-17.
All of the Sigma/Tamron 10-2x lenses fall short if you expect IQ in line with your other lenses. The best zooms here are the Sigma 8-16 and the Tokina 11-16 (but unfortunately the later isn't even available in Pentax mount). The Sigma still shows some of the Sigma rendering (which I don't like), but not as much as some other Sigmas, and it's super sharp (as in
impressively so).
That leaves the DA12-24, which is too expensive and too much compromise in IQ, especially when it doesn't even give you enough additional range over what you currently have, and has further compromised its IQ by redundantly covering 16-24mm for you again (which is why I wish the Tokina 11-16/2.8 were available in K-mount).
Remaining is the Samyang (/Rokinon/others) 16/2, 14/2.8, and (hopefully in less than about 6 weeks, if reports are correct) 10/2.8. I don't completely like the colors from the Samyang lenses, but the IQ is pretty good overall. The 10/2.8 is the one I'm most interested in - probably the one you should consider too.
So, since you look for top IQ like I do, I'd say:
DA15 (the best choice if it's wide enough - DA*16-50 is a little weak wider than 20 or 18mm)
Sigma 8-16 (great from 10-16mm, and completes your range well)
Samyang 10/2.8 (if it's as good as their current lenses - and it probably will be)
DA10-17 in conjunction with DA15 completely did the trick for me - at least until I had to do some tight architectural interior shots with minimal distortion (that was when I added the Sigma 8-16). You can actually go quite wide on landscapes with the DA10-17 without making it look weird if you're willing to put the horizon right in the middle of the frame.
PENTAX : Select a PENTAX interchangeable lens camera or a lens model