This is a hard question to answer. Each focal length has its own charms.
My current favorite is the Rokinon 85mm f/1.4. Just the thing for doing bokeh. It works well for regular photography too.
Historically, it would be the SMC Pentax M 200mm f/4 - very compact for a 200mm. It was the first Pentax lens that I bought new and has seen a
lot of use over the years. These days, it sits in a dark place. I really must take it for an outing.
Two lenses that have rediscovered this year are the SMC Pentax M 20mm f/4 and SMC Pentax M 28mm f/2.8 - just right for street photography. Compact, sharp and at f/11 you don't have to mess around with focus - just point and shoot.
PS: I don't have any manual focus zoom lenses.