You seem like you probably have the Pentax and Takumar lineup pretty well understood. Quite a few 135s and a 120 to look at.
Here are some others I know of that might be worth looking into:
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Tokina 90mm macro: known as Bokina for it's special bokeh. A little shorter than you're looking for and pretty close to 77.
-Pentax 100mm macro (f/fa/dfa): as others mentioned it does fine for portraits. Just a very useful lens.
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Vivitar 135 macro: there are a few good versions, and a few Vivitar 135s that aren't as great. This one has always had my interest, although I've never pulled that trigger and don't find myself needing it.
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Samyang 135 and
Mitakon 135: Two modern designed MF lenses at a great price. I know the Samyang is always mentioned for astro, which is about as demanding on a lens as possible, but doesn't guarantee pleasant bokeh.
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Irix 150 macro: longer than you were thinking, but not by a ton, and it's another one that would add more than just portraits to your kit. I've not read how good it is for that purpose, tho. Nice that it's WR, too.
Not recommendations, I'm just throwing them out there in case you weren't aware of any of those. I have FA100mm Macro and think it would be okay for what you're looking for, but I could also believe someone would want a more characterful or interesting lens for doing artful portraits. 100 macro feels a bit like a precision tool.