Where to start. ... Limiteds ....the finest primes on the planet
well, I think they are. I am excluding FA limited purely on price. DA limiteds range from £150-300. They all have a very special way of rendering. The pancakes (21, 40 & 70) are small enough for you to fit your camera and lens in a jacket pocket
15mm f4, lovely wide angle lens with legendary star bursts on the SMC version
21mm f3.2. Full of pixie dust, pancake, and flexible enough to use all day. Very sharp and quite inexpensive.
35mm f2.8 macro. Great all rounder. I used mine exclusively on a visit to Cadiz
40mm f2.8. Very similar to your XS, the only difference really is the look. Stunning lens
70mm f2.4. Quite fast and very sharp
Other superb lenses
FA 35mm f2 sharp, fast and cheapish
50mm f1.8 plastic fantastic. A brilliant performer for well under £100
The 15 & 70 can't really be called a walkabout but any of the others could sit on your camera all day. Primes enrich you photographically. The IQ is often, (but not always) better because their construction is generally simpler. As for using them, they make you think about composition because you have to zoom with your feet.