Originally posted by ColiNiloK And which metering mode on Pentax is the most "accurate"?
It depends on the lighting, the scene - and the lens.
Some older lenses (or even newer non-Pentax brand lenses, perhaps) may only work in centre-weighted average metering mode.
If I am using telephoto and shooting for example small birds I will usually choose centre-weighted because all the subject is going to be in the centre. If I am shooting a landscape scene or cityscape with a wide angle lens I will choose matrix metering. If I am shooting a band in very low-light with say a lens like the FA50 1.4, I will usually switch to centre-weighted because I don't need to have all the dark background clutter on stage metered, just a single performer, and because of this centre-weighted will also let me use lower ISOs or faster shutter speeds.
You may also like to check that you don't have 'link AE to AF point' checked on your camera. That could be skewing your AE in unexpected ways.