Originally posted by RGlasel IR should still require line of sight to work, my O-Rc1 remote certainly does.
It does, but it can also be easily bounced off most surfaces. IR frequency is just below that of light visible to the human eye. On your sample (good example of IR's capability by the way), if you can see the flash from the Metz, the Metz can see the IR emitted from the pop-up flash. IR is also subject to the other limitations of visible light too, specifically it weakens with the square of the distance and can be absorbed to some extent by whatever surfaces it bounces off of.
There is one other aspect to communication via encoded signals transmitted by IR, and that is interference from other IR sources. The sun, for example, is a
huge IR emitter. The IR from the sun is in the form of white noise rather than an encoded signal, so it doesn't trigger IR receivers, but at the same time, IR receivers will have problems seeing an encoded signal from smaller IR sources when the sun is present. It is like trying to see a small pen light with a big floodlight next to it. Now, unless you are trying to do fill-flash wirelessly on a sunny day, the sun won't have much impact on our flash issue - a more common issue is with wireless remote releases - but I am using it here as an extreme example. The same issue would occur to a much smaller extent with other IR sources such as heat lamps, TV remotes sending a signal at the same time in the same vicinity of the flash, and so on.