I had to hand my Sigma 8-16mm f/4.5-5.6 ASPH DG back into the shop - the decentering was really getting in the way of me making a proper comparison with the DA15mm f/4, the thing is the rest of the images from the lens were fine apart from the extreme left hand side and it was
really bugging me. The Pentax K5IIs has zero tolerance towards optical faults* - if there is a flaw in the lens the camera will reveal it in pristine clarity. Personally I prefer to use the Zeiss Star chart, projected through the lens mounted on a specialised optics testing bench - the Zeiss pattern which has been used to spot problems like this in photographic optics for decades. However a really quick way to spot decentering is to shoot one frame with a finely textured subject that is preferably at infinity focus with the camera normally - then flip the camera upside down and take a shot with identical framing. Using the comparison tool in Lightroom to show the images side by side - if they look Identical then you have a perfectly aligned lens, if they don't look the same and one part of the image is sharper than the other: Then there is a problem.
My pentax DA15mm f/4 ED ASPH Limited was perfect right out of the shop - a
big win for the pentax lens.

Sigma 8-16mm at 8mm showing the degree of decentering I discovered, Image produced by the method outlined above - crops are from the extreme Right corner @ 100% unsharpened
*Neither do I.