I have a couple of SYK-3 optical triggers, they are sold under many names including Cowboystudio, I have used them with a couple high voltage flashes without a problem. I've seen reports from other people saying that they have no problems with 200V+ flashes either. The manufacturer or sellers will not give an official statement on their voltage handling capabilities though, other than saying 12V is considered safe and they might not trigger reliably if the flash is below 6V. There is always the possibility you will kill one though, so it would be good to keep spares.
Your Sigma is going to have to be in full manual mode, these triggers will not sync properly if you have the TTL pre-flash. The SYK-5s have a delay setting for pre-flash, but I don't know how well they do with high voltage flashes. It is preferred to be in manual mode anyway, mixing TTL and manual flashes can be unpredictable.
This is where I got mine from:
Seagull Infrared Flash Remote Trigger for Digital Camera SYK-3 - Free Shipping - DealExtreme