I have found a picture and description that refers to a small oblong plug (that is missing from my unit)
Google translate describes it as "synchronizer with applicable on camera or a second flash" and it would appear to go between the sync cord and the flash.
I think it might just be a form of daisy chaining but ???? Thoughts..?
Anyone with a manual they could scan and email...?
Also found another translation that has the user operating it from ...
Quote: UNOMAT P450 TCS set to AUTO Thyristor connected to the optical trigger with 5 SYK function prelampi
activated
so a SYK-5 the same as I have.
Curiouser and curiouser said Alice.
EDIT-SOLVED
Ah, the wonders of percussive maintenance !!
I had the flash off its stand and was trying to fire it whilst handholding.
It worked..!

....once, then not again

But that was enough of a clue and a few good slaps found the problem.
The on-off switch has lost its internal springiness to keep the contacts pressed tight. It must be passing enough current to initialise charging but not to allow triggering.
By turning it on and holding it down all works.

(why it should work for direct short trigger but not slave trigger is a mystery but perhaps there is an interlock with the thyristor that is not happening unless the switch is held down..??)