Make some tests. Get a friend to stand where you feel the couple and the AB will be on a bright sunny day as you anticipate.
Then you change settings until you are satisfied. You start with those settings at the location.
If you are getting over exposure because the sun is too bright and fstop and ISO settings are maxed out, dont be shy about stopping down more. Even going as far as f22.
The idea is to get the shot worry about possible diffraction later. Most non photograhers will not see this.
I was in your boat two weeks ago. The guys here were very helpful
Help! Wedding photoshoot planning. - PentaxForums.com
Culture.