Originally posted by Ray Pulley
Just like a prism, CA is a refraction problem, so a optic that has very specifically designed diffraction properties can offset the refraction. This is not the only way to correct for CA, but there must be some other reason (cost, size, etc.) to choose this technology over the other methods. Perhaps it is also more accurate?
I don't know a huge amount about the AF system design. However, I'd like to add that any optical system can benefit by increasing the number of optical elements. MTF especially can improve, and being able to discern finer detail does seem like it should translate to better focusing. A diffractive optical element (DOE) is basically like a singlet lens, except it is flat (very similar to a Fresnel lens).
I agree that if the DOE is tailored to compensate for chromatic aberration, that could also be a big plus. However, I'd be a little bit concerned about the wavelength sensitivity of the DOE--it may work really well in most kinds of lighting situations, but could still choke.