Originally posted by mikeSF have model step aside and shoot that brick chimney or a suitable brick wall using a tripod to maintain precise focusing distance and be sure camera is perfectly level when shooting a perpendicular wall.
Originally posted by ntrao Looks to me a little lens issue. To my knowledge, the entire plane should be sharp or off at whatever aperture, not just one half or the other.
Agreed you need to run a better test to go thru a process of elimination.
Are you using OVF AF or LiveView or MF?
If with a flat surface perpendicular to your lens you get the same problem at f/2.8 at that focal length regardless of focusing technique, then it's the lens that is de-centered.
Keep in mind that the center of your lens will be sharper than the corners and edges at large apertures and wide angle.
If the problem can't be replicated with a flat surface centered at lens level, then it was probably an AF fine tuning problem that can be corrected in the menu. Typically you'll get your best AF with Live View. If MF, zoom into the focal point of your shot (like her face), focus, and then without changing the focus, zoom out.