So sorry to hear about the problems with the screen install. I have a K20, which doesn't use shims, and the Chinese prism slipped right in--no problems. The frame for the screen both seats and centers it.
I'm not sure why you have centering problems. It could be you have the wrong sized screen, though I doubt it. If a shim came out of there, there is a good chance one needs to go back in there--it depends on the new screen's thickness. No problem though. Just measure the old and new screen with a micrometer. I would use one of those newer, plastic models on the screens. can get them cheap nowadays and they often come in handy==Sears has them, but even cheaper from large, no name tool warehouses, like Harbor Freight.
First, take a measurement of both screens' height and length--any difference here would explain the centering problem. Next, take a measurement of the width of both screens. If both screens are identical, then use the same shim. If the new screen is thicker, subtract the difference of the old screen and then you know what, if any, shim to use. And if the new screen is thinner, you know you need a shim. Just add the difference by which it is thicker to the original shim and you have the thickness for a new shim--order from Pentax.
(edit:by use of the word "width," I mean the screen's thickness) For example: new screen measures .8mm thicker than original screen--in this case you do not need a shim.]
Here are directions for installing a prism in the K200d--they are for the Katz eye, but obviously apply to other screens as well.
http://www.katzeyeoptics.com/files/install6.pdf