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First of all, many think that AA's are good enough. I'm not questioning that, it just that you can always wish for something better. So please lets not discuss if AA's are good but actual topic.
Replacing AA batteries with a stable, powerful and well designed rechargeable Li-Ion is not possible because of the small space available for AA's. But you can easily fit a whole switched mode power supply unit in a grip, leaving a plenty of space.
This would allow for high current capable voltage stabilization, that does not waste power in heat to be used with heavy duty lithium battery.
*Is there already such thing?
*Do you think the gain is worth making one? (no need to design one, just replace the internals of some cheap 3rd party grip with readily available stabilization and lithium control circuits)?
-you could answer this, if you've used non rechargeable Li Ion AA's or external power supply - how much the camera performance and shot count increases.
*To save some weight.. does the camera work with power from grip but without batteries in camera?
How important it would be to foresee the possibility to change batteries? - it is MUCH easier to simply make it built in, with such a DIY design - especially if you wish to retain weather sealing.