This link may be helpful:
Explaining “Image Resolution” and View > Print Size | Photography Tutorials | Planet Photoshop
If I want to view my image at it's real print size, I take my monitors width in inches, then divide that by it's horizontal resolution to get the monitors real pixels per inch(PPI). Then you take your monitor's PPI and divide it by your print DPI and you get the percent to use in the navigator. Strange to explain easy to do.
For example, my monitor is somewhere around 106-108 PPI. I take 106/360= ~29.5% or if I'm printing at 180 DPI, I'll get 106/180=~59%.
I'll admit, that's kind of a silly way to do things
... unless you need to actually see something at it's real size. Most times I'll just check an image at 33, 50, 66, and 100% to make sure it looks good before sending it to print. I'll also sometimes bring an image up to 100% and then stand about 3-4x further back, helpful for checking how fine details might appear in the final print.