Final installment regarding my new second PC...
I now have two identical Crucial DDR3L-1600 8GB UDIMMs installed, one in each of the two available slots. However, it seems that with two UDIMMs installed, the speed drops from 1600MHz to 1333MHz. I initially thought this was a fault with one or both of the cards, but after digging around online it seems it's a limitation of the processor and single channel memory architecture (each card, when installed on its own, shows up as 1600MHz). A bit of a shame, but it shouldn't have too much of an impact on performance.
Running Darktable, I can't honestly say I notice any significant difference in performance whether I have 8GB or 16GB installed... In either configuration, it runs better than I expected, yet not exactly brisk
No way is it a full-time photo processing setup, but it's perfectly adequate for occasional RAW, TIFF and JPEG work. Not bad considering it's at the low end of current desktop PC specs