Just to clarify the question, are you asking why digital cameras have more chromatic aberrations with new lenses built for them or with old lenses, high end lenses or cheap ones? Also are you clear on the difference between C.A. and purple fringing? I sometimes get purple fringing with wildly different contrasts (recently with back lit stain glass in a church) but closing a stop or two clears it right up.
Not sure about C.A. since I never really see any of that even with my old A lenses I use. Anything but new glass optimized for the requirements of digital would in theory cause more C.A. They've both improved with computer design and tweaked in general the characteristics of new stuff to keep the sensors happier.
Plus what Adam said, film is just better.
EDIT: Ok I guess these old A's do make some C.A. (depending on contrasting light) I just had to zoom WAAAAY in to see it (like Mario Brothers level of pixelation zoomed in), and since I am in the habit of cropping by zooming or just moving when using a prime to get better quality full size photos, I just never saw it before.