Originally posted by Na Horuk One other thing is that metering works in a different way. It looks at the overall brightness (in the areas where it is metering) and then adjusts settings according to algorithms. What you want it to do, is look only for the brightest part in the frame, and expose in such away, that the highlight retains enough information, but is as bright as possible. I'm sure there could be a way to make such a metering system, but I don't think any camera has it. You might get close by using something like a configurable trigger, possibly with its own lightmeter, but even then you risk metering the light outside of the photo frame. And it would be a DIY project, I don't know of anyone doing this so far (but would be interested to see)
Depending on the situation I have often walked in close to a scene and spot metered on the highlights, locked the exposure with AE-L lock, backed up, recomposed and pulled the trigger.
It can work well depending on the situation but really should, and could?, be implemented in camera. Maybe some day.