There are a couple differences between the Samyang 14mm and 16mm.
14mm has slower aperture, doesn't take filters, cannot remove lens hood (which is made for FF). The 16mm is made for APSC and not FF.
There is also a small difference in the angle of view, which can be noticeable.
I got a 14mm back when it first came out, but I usually recommend the 16mm now (despite not owning one). It is less awkwardly wide, probably easier to focus (more telephoto, faster aperture) and has brighter aperture, and I haven't seen so many QC problems reports! And this might be a big issue. The Samyang 14mm is a great, sharp lens, but so many users on this forum (and elsewhere) had to return the lens due to decentering problems. And the distance scales are usually wrong. You can adjust them yourself, there are blog posts and videos about it, because it is important to know where the lens has true infinity and hyperfocal, especially for astrophoto because you are out in the dark, often in cold, being attacked by mosquitoes
But I don't actually have the 16mm on hand to compare, and I haven't done much astrophoto. I'm just saying that if I were buying today, I would get the 16mm. The new 20mm is tempting as well, but it is more expensive, has not been reviewed much yet, and it is significantly less wide. I don't think 20mm can replace a 14mm, but it can be used alongside.
Edit: One more thing is that Samyang (especially the 14mm) is sold under various names, like Rokinon, Walimex, Bower, ProOptic, Falcon.. sometimes these come at different prices, but they are optically all the same as far as we know. It might be worth to look for some other names, you can save a couple bucks, but always buy from a reputable store with warranty guarantee, due to the QC issues!
Last edited by Na Horuk; 10-14-2016 at 04:28 PM.