In real world use (which is the only use that counts) Sunny 16 has got a lot in common with the zone system. For example, in this one from last year the directly sunlit areas of grass fell within my usual "Sunny 16" of f/11 at 1/125 at ISO 100, but using that exposure would have drastically underexposed the shaded areas. I knew that with the GX-10 (K10D) that I was using I could overexpose the sunlit areas by two stops and still have usable detail in the raw file -- in other words put them in Zone VII -- so that's what I did by exposing at f/8 at 1/60 at ISO 100. It still left the shaded areas underexposed but within the range that I could recover in Camera Raw, and it meant that there would be some unimportant small patches blown to white, but it was the best compromise to get a workable raw file.
So in terms of practical application, using Sunny 16 is very similar to using the zone system, but doing it by eye rather than with a spot meter.