Canvas will tend to give you a softer, more "painterly" look. The photos probably will not look quite as sharp as they might on something like a glossy paper. That may or may not be good - depends on the photo.
The frame is usually called a "stretcher frame". You can get the photo stretched around the outside of the frame, so it's sort of a wraparound. Alternatively, you can get it with a sort of border on the sides. I think the first kind is called a "gallery wrap" and the second is a "museum wrap."
There are a number of places online that you can get it done. I've never used any, but Mpix.com does canvases and I've used them for other kinds of prints and been happy.
Good luck, hope it turns out!
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