Colour rendition is not dependent on ccd or cmos but the colour filter array:
Color filter array - Wikipedia It is largely very subjective anyway.
Dxo mark scored both camera's (and removed the 645z again because it broke their scoring mold).
645d
Overall Score 82
Portrait (Color Depth) 24.6 bits
Landscape (Dynamic Range) 12.6 Evs
Sports (Low-Light ISO) 1262 ISO
645z
Overall Score 101
Portrait (Color Depth) 26 bits
Landscape (Dynamic Range) 14.7 Evs
Sports (Low-Light ISO) 4505 ISO
As you can see colour depth is deeper on the 645z so potentially more accurate. Dynamic range is much better and noise performance is much better. Meaning cleaner more usable images. People mainly like ccd because they say it looks more like film. Not because it is more accurate. Film wasn't accurate. You can make any picture look like film. There is a ton of software for that.
Also the Z has the AF sensor of the K-3. Though limited to the centre of the image, it is much faster than the one in de D. It's like going from a Pentax K10D to the K-3. A world of difference.
---------- Post added 24-12-16 at 14:36 ----------
This is the same shot both with the Pentax SMC-M 40mm F2.8 one with the K10D (ccd), one with the K-5 (cmos). I've adjusted exposure to match and eye dropped white balance from the same point.
Can you tell which is which?