Can you post a photo of the top of the adapter?
The PC contact is activated by a switch in the camera, just like a light switch. Where the ball in the foot of the flash rests in the adaptor must be conductive.
PS
It sounds like you might have the wrong adapter; yours might be one that is meant to be placed in the hotshoe of the camera to give a PC output (for cameras like a K10D that does not have a PC output).
Is this what yours looks like (image borrowed from bhphotovideo)?
You need one that has a contact in the center on the top. Something like this (image borrowed from amazon)
Or like this (borrowed from bhphotovideo)