Originally posted by mattt Looks like foamy residue from the mirror bumper. Very common in old cameras that have not been maintained. A CLA (Clean Lubricate and Adjust) would repair this situation.
...or something like that. What do you see when you take the lens off and look into the mirror box? Is there junk on the mirror or focus screen? If so, removal typically requires the services of a camera repair shop. The mirror and focus screen are very delicate and are easily scratched. There is also the risk of knocking the mirror out of alignment. The general rule for both screen and mirror is, "Do Not Touch".
One of the hazards of buying a vintage camera is that the foam materials used for light seals around the film door and as a mirror bumper are prone to disintegrate with age. Often this means a gooey sticky black mess that can foul the mirror and/or the focus screen. There is also the risk of the fragments being flung onto the shutter curtains. While often impractical, it is good to check the condition of the foam before shooting with the camera. This is done be touching the foam with a toothpick or similar sliver of wood. If the foam is sticky, crumbly or anything other than springy, it should be replaced. If the mirror and screen have not been fouled, replacement may be done as a do-it-yourself project using a kit such as that offered by Jon Goodman.
Steve