Originally posted by boriscleto From the Pentax manual... For deliberate multiple exposures, make the first exposure in the normal way. Then tighten the film by turning the rewind knob, and keep hold of the rewind knob. Depress the film rewind release button, and cock the rapid-wind lever. This cocks the shutter without advancing the film. Finally, release the shutter to make the second exposure. Then make one blank exposure, before taking the next picture, to avoid overlapping as registration may not be exact.
I'll add one more thing... you also need to deliberately under-expose both images if there is any overlap of subjects. Otherwise you'll burn out all the highlights. Think about it this way, if a scene meters at 1/125 and f/5.6, and you double-expose an identical frame twice at 1/250 and f/5.6, the film will have the same exposure as a single shot at 1/125 and f/5.6.
An exception and common way to double expose is to use a completely dark studio with a black background and the subject wearing black. Use a tight spot on the subject's face and compose the first shot with the subject in one corner of the frame. Then change the angle of the subject's face and/or the lighting angle, and the lens to subject distance and compose with the subject in a different corner. Because of the full black, both shots are at normal exposure using spot metering.